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Definitions and Properties of Acids and Bases

  ACIDS BASES
Examples

Mineral Acids:

  • hydrochloric acid,HCl
    cleaning metals and mortar,
    used in swimming pools to adjust pH,
    found in stomach

  • sulfuric acid, H2SO4
    used in car batteries,
    used to make fertilizers (sulfate of ammonia and superphosphate),
    plastics, detergents, dyes, drugs, explosives

  • nitric acid,HNO3
    used in the manufacture of fertilizers, explosives (TNT and dynamite)

  • phosphoric acid,H3PO4
    used as a food acid and in anti-rust products for cars

Organic Acids:

  • methanoic acid (formic acid), HCOOH
    found in ant stings

  • ethanoic acid (acetic acid), CH3COOH
    found in vinegar

  • butanoic acid (butyric acid), C3H7COOH
    the acid that gives rancid butter its characteristic smell

Alkalis (water soluble bases):

  • sodium hydroxide, NaOH
    caustic soda

  • potassium hydroxide, KOH
    caustic potash

  • aqueous ammonia, NH3(aq)
Properties aqueous acidic solutions:

  • sour taste

  • turn blue litmus red

  • electrical conductors

  • corrode most metals

  • react with carbonates and bicarbonates

  • neutralise bases
aqueous solutions of bases (soluble bases are called alkalis):

  • bitter taste

  • change red litmus blue

  • electrical conductors

  • slippery feel

  • neutralise acids
Arrhenius Definitions
(1884)
an acid ionises in water to produce hydrogen ions, H+ (protons) a base ionises in water to produce hydroxide ions, OH-
only accounts for acids that:

  • are aqueous solutions

  • have hydrogen ions in their structure, eg, HCl

does not account for amphoteric substances
(those that can act as an acid or a base)

only accounts for bases that:

  • are aqueous solutions (alkalis)

  • have OH- already in their structures, eg, NaOH

does not account for amphoteric substances
(those that can act as an acid or a base)

Brönsted-Lowry Definitions
(1923)
an acid is a species that donates a proton (H+) a base is a species that accepts a proton (H+)
an amphiprotic substance can act as a proton donor and as a proton acceptor
hydrogen carbonate (bicarbonate) ion (HCO3-)is amphiprotic, it can either accept a proton to form carbonic acid (H2CO3) or it can donate a proton to form carbonate ion (CO32-)
HB H+ + B-

HB is acting as an acid by donating a proton, H+
B- is the conjugate base of the acid HB
B- + H+ HB

B- is acting as a base by accepting a proton, H+
HB is the conjugate acid of the base B-
acid conjugate base
HCl Cl-
HNO3 NO3-
H2SO4 HSO4-
HSO4- SO42-
H2O OH-
base conjugate acid
OH- H2O
NH3 NH4+
CO32- HCO3-
HCO3- H2CO3
H2O H3O+
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Related AUS-e-TUTE Topics

Defining and Using pH and pOH

Acid Dissociation Constants (Ka)

Base Dissociation Constants (Kb)

Acid Base Titration Calculations

Acid Base Titration Curves (graphs)

Indicators for Acid Base Titrations

 
 

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