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Displacement Reactions

Some Standard Reduction Potentials

Oxidants

 

Reductants

E0
(volts)

Weakest
Oxidant
K++e K(s) -2.94 Strongest
Reductant
Ba2++2e Ba(s) -2.91
Ca2++2e Ca(s) -2.87
Na++e Na(s) -2.71
Mg2++2e Mg(s) -2.36
Al3++3e Al(s) -1.68
Mn2++2e Mn(s) -1.18
Zn2++2e Zn(s) -0.76
Fe2++2e Fe(s) -0.44
Ni2++2e Ni(s) -0.24
Sn2++2e Sn(s) -0.14
Pb2++2e Pb(s) -0.13
Cu2++2e Cu(s) 0.34
Strongest
Oxidant
Ag++e Ag(s) 0.80 Weakest
Reductant

Key Concepts

A more active metal will displace a less active metal from solution.
  • A more active metal

    (i) loses electrons more easily

    (ii) is the stronger reductant

    (iii) is the weaker oxidant

    (iv) has a lower standard reduction potential

  • The less active metal

    (i) is less likely lose electrons

    (ii) is the weaker reductant

    (iii) is the stronger oxidant

    (iv) has a higher standard reduction potential

An activity series places metals in order from most active to least active.

 

Examples of Displacement Reactions

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