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Down's Cell for the Production of Sodium

Key Concepts

  • Sodium metal can be extracted electrolytically from molten (fused) sodium chloride using a Down's Cell.

  • Calcium chloride or sodium carbonate is added to reduce the melting point of sodium chloride.

  • Electrolysis of molten (fused) sodium chloride produces sodium metal and chlorine gas.

  • In the Down's Cell a circular iron cathode surrounds the carbon anode and the products of the electrolysis are separated by steel mesh or gauze to prevent them coming into contact and reforming sodium chloride.

  • The amount of sodium produced can be calculated using Faraday's Laws of Electrolysis.

Down's Cell Example

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Related AUS-e-TUTE Topics

Electrolysis of Molten Salts

Electrolysis of Aqueous Salt Solutuions

Electrolysis - Electrolytic Cells

Oxidation and Reduction

Displacement Reactions

Faraday's Laws of Electrolysis

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