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Mole-Number of Particles Calculations

Key Concepts

  • 1 mole of any substance contains 6.022 x 1023 particles.

  • 6.022 x 1023 is known as the Avogadro Number or Avogadro Constant and is given the symbol NA or L

  • To find the number of particles in a mole of substance, multiply the moles by the Avogadro number:
    1 mole contains 6.022 x 1023 particles
    2 moles contains 2 x 6.022 x 1023 = 1.204 x 1024
    10 moles contains 10 x 6.022 x 1023 = 6.022 x 1024
    0.5 moles contains 0.5 x 6.022 x 1023 = 3.011 x 1023

  • This leads to the equation: N = n x NA
        where N = number of particles in the substance
        and n = moles of substance
        and NA = Avogardro Number = 6.022 x 1023 particles mol-1

  • To find the number of particles, N, in a substance: N = n x NA

  • To find the moles, n, of substance, n = N/NA

Examples

Find the number of particles

1. Find the number of ammonia, NH3, molecules in 3.5 moles of ammonia.
  1. Extract the data from the question:
        moles of ammonia, n(NH3) = 3.5 mol
        number of ammonia molecules, N(NH3) = ?

  2. Write the equation: N(NH3) = n(NH3) x NA
        NA is the Avogadro constant = 6.022 x 1023 molecules mol-1

  3. Substitute in the vales and solve:
        N(NH3) = 3.5 x 6.022 x 1023 = 2.1 x 1024 ammonia molecules

2. Find the number of hydrogen atoms in 1.5 moles of water, H2O.

  1. Extract the data from the question:
        moles of water, n(H2O) = 1.5 mol
        number of H atoms, N(H) = ?

  2. Calculate the moles of H atoms present in 1.5 mol H2O:
        From the chemical formula we see that 1 molecule of water is made up of 2 atoms of hydrogen and 1 atom of oxygen.
        So, 1 mole of water molecules contains 2 x 1 = 2 moles of hydrogen atoms.
        Therefore 1.5 moles of water molecules contains 1.5 x 2 = 3.0 moles of hydrogen atoms.
        n(H) = 3.0 mol

  3. Calculate the number of hydrogen atoms using the equation N(H) = n(H) x NA
        N(H) = 3.0 x 6.022 x 1023 = 1.8 x 1024 hydrogen atoms.

Find the moles of substance

1. A sample of gas contains 4.4 x 1024 carbon dioxide molecules.
    How many moles of carbon dioxide are present in the sample?
  1. Extract the data from the question:
        Let N(CO2) be the number of carbon dioxide molecules
        N(CO2) = 4.4 x 1024 molecules
        moles of CO2, n(CO2) = ?

  2. Write the equation: N(CO2) = n(CO2) x NA
        where NA, the Avogadro constant, = 6.022 x 1023 molecules mol-1

  3. Rearrange the equation to find n(CO2):
        n(CO2) = N(CO2)/NA

  4. Substitute the values into the equation and solve:
        n(CO2) = 4.4 x 1024 / 6.022 x 1023 = 7.3 mol

2. A sample contains 2.4 x 1022 molecules of oxygen gas (O2).
    How many moles of oxygen atoms are present in the sample?

  1. Extract the data from the question:
        Let N(O2) be the number of oxygen gas molecules
        N(O2) = 2.4 x 1022 molecules
        moles of O atoms, n(O) = ?

  2. Calculate the number of oxygen atoms present:
        1 molecule of O2 contains 2 molecules of O atoms
        2.4 x 1022 O2 molecules contains 2 x 2.4 x 1022 O atoms
        N(O) = 2 x 2.4 x 1022 = 4.8 x 1022 O atoms

  3. Write the equation: N(O) = n(O) x NA
        where NA, the Avogadro constant, = 6.022 x 1023 molecules mol-1

  4. Rearrange the equation to find n(O):
        n(O) = N(O)/NA

  5. Substitute the values into the equation and solve:
        n(O) = 4.8 x 1022 / 6.022 x 1023 = 0.08 mol
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